Transition-Metal-Free Cross-Coupling of Aryl Halides with Arylstannanes.
نویسندگان
چکیده
Transition-metal-free LiCl-promoted cross-coupling reactions of tetraphenyltin, trichlorophenyl-, dichlorodiphenyl-, and chlorotriphenylstannanes with aryl halides in DMF provided access to biaryls in good to high yields. Up to four phenyl groups were transferred from the organostannanes substrates. The aryls bearing electron-withdrawing groups in either halides or organotin substrates gave coupling products in higher yields. The methodology has been applied for the efficient synthesis of ipriflavones.
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 81 19 شماره
صفحات -
تاریخ انتشار 2016